Binding of an Acetonitrile Molecule Inside the Ethereal Cavity of a Hexaarylbenzene-based Receptor Via a Synergy of C-h...o/C-h...pi Interactions.
From: Department of Chemistry, Marquette University, PO Box 1181, Milwaukee, WI 53201-1881, USA.
Chemical communications (Cambridge, England)
- Publish Date: Sep 2007
- ISSN: 1359-7345
- Volume:
- Issue: 36
- Pages: 3717-9
- Medium: Print
- Language: English
- Citation (JAMA): Shukla Ruchi, Lindeman Sergey V, Rathore Rajendra, et al. Binding of an Acetonitrile Molecule Inside the Ethereal Cavity of a Hexaarylbenzene-based Receptor Via a Synergy of C-h...o/C-h...pi Interactions.. Chem. Commun. (Camb.) Sep 2007;:3717-9
Abstract
A pair of hexaarylbenzene-based receptors, which contain a circular, as well as a partially-broken, ethereal fence around the central benzene ring, bind acetonitrile molecules via a synergy of C-H…O and C-H…pi interactions, as probed by X-ray crystallography.
Mesh Headings (Keywords): Acetonitriles, Benzene Derivatives, Binding Sites, Crystallography, X-Ray, Molecular Conformation, Molecular Structure
Check for Full Text / PubMed Unique Identifier (PMID): 17851605
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